A nitrido salt reagent of titanium.

نویسندگان

  • Rick Thompson
  • Chun-Hsing Chen
  • Maren Pink
  • Gang Wu
  • Daniel J Mindiola
چکیده

Deprotonation of the parent titanium imido ((tBu)nacnac)Ti≡NH(Ntolyl2) ((tBu)nacnac(-) = [ArNC(t)Bu]2CH; Ar = 2,6-(i)Pr2C6H3) with KCH2Ph forms a rare example of a molecular titanium nitride as a dimer, {[K][((tBu)nacnac)Ti≡N(Ntolyl2)]}2. From the parent imido or nitride salt, the corresponding aluminylimido-etherate adduct, ((tBu)nacnac)Ti≡N[AlMe2(OEt2)](Ntolyl2), can be isolated and structurally characterized. The parent imido is also a source for the related borylimido, ((tBu)nacnac)Ti═NBEt2(Ntolyl2).

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عنوان ژورنال:
  • Journal of the American Chemical Society

دوره 136 23  شماره 

صفحات  -

تاریخ انتشار 2014